{"created":"2023-06-19T07:24:18.413748+00:00","id":10131,"links":{},"metadata":{"_buckets":{"deposit":"4e63629e-5ba0-4a62-84e0-dafa8ca1c112"},"_deposit":{"created_by":5,"id":"10131","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"10131"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00010131","sets":["147:191"]},"author_link":["15118"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1995-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"17","bibliographicPageStart":"1","bibliographicVolumeNumber":"44","bibliographic_titles":[{"bibliographic_title":"岐阜藥科大學紀要"},{"bibliographic_title":"The annual proceedings of Gifu College of Pharmacy","bibliographic_titleLang":"en"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ARAI, YOSHITSUGU","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"15118","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"This review reports on our recent studies on asymmetric Diels-Alder reactions of chiral α, β-unsaturated sulfoxides. For the preparation of these sulfoxides as Diels-Alder dienophiles, the Andersen method as well as a novel route by diastereoselective oxidation of 2-exo-hydroxy-10-bornyl vinyl sulfides with 3-chloroperoxybenzoic acid is presented. The latter methodology has been successfully applied to synthesis of two types of novel sulfoxides bearing labile fuctionality, I.e., α-sulfinylmaleate and α -sulfinylmaleimide derivatives. These sulfinyl dienophiles effect Diels-Alder reactions with a high degree of diastereoselectivity. Especially, the chiral α-sulfinylmaleimides readily react with Diels-Alder dienes of rather low reactivity, to give the corresponding cycloadducts under conventional conditions. Also described are applications of these asymmetric Diels-Alder reactions to natural product synthesis.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00053514","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Laboratory of Pharmaceutical Synthetic Chemistry, Gifu Pharmaceutical University"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"岐阜薬科大学"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1995-06-30"}],"displaytype":"detail","filename":"KJ00000073153.pdf","filesize":[{"value":"776.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://gifu-pu.repo.nii.ac.jp/record/10131/files/KJ00000073153.pdf"},"version_id":"133f3767-9af7-46f0-a48c-c725479aee5d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<Review>Asymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<Review>Asymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles","subitem_title_language":"en"}]},"item_type_id":"1","owner":"5","path":["191"],"pubdate":{"attribute_name":"公開日","attribute_value":"1995-06-30"},"publish_date":"1995-06-30","publish_status":"0","recid":"10131","relation_version_is_last":true,"title":["<Review>Asymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2023-06-19T09:06:22.636818+00:00"}