{"created":"2023-06-19T07:24:45.175012+00:00","id":11689,"links":{},"metadata":{"_buckets":{"deposit":"fb1796b9-70b3-4203-bfac-fe74d2b15b9c"},"_deposit":{"created_by":5,"id":"11689","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"11689"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00011689","sets":["147:195"]},"author_link":["16670","16671","16669"],"item_1_alternative_title_5":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_alternative_title":"〓"}]},"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"19","bibliographicPageStart":"9","bibliographicVolumeNumber":"48","bibliographic_titles":[{"bibliographic_title":"岐阜藥科大學紀要"},{"bibliographic_title":"The annual proceedings of Gifu College of Pharmacy","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"岩間, 哲男"}],"nameIdentifiers":[{"nameIdentifier":"16669","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"イワマ, テツオ"}],"nameIdentifiers":[{"nameIdentifier":"16670","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"IWAMA, Tetsuo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"16671","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"1,2-チアゼチジン1,1-ジオキシド(β-スルタム)は,β-ラクタムのスルホニル類縁体またはタウリンの環化生成物と見なすことができる。このため,β-スルタムは,化学的および薬学的な観点から研究がなされてきた。Β-スルタムは三種類の異なるヘテロ結合(C-S, C-N, N-S)により構築された歪みの大きい4員環構造を有している。Β-スルタムのヘテロ結合を選択的にヘテロリティックに開裂することができれば,β-スルタムを2-アミノエチルカチオン,2-アミノエタンスルホニルカチオンや2-スルファモイルエチルカチオン等の合成等価体としてみなすことができる。Β-スルタムのヘテロ結合の開裂反応について解説する。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"1,2-Thiazetidine 1,1-dioxides (β-sultams) are sulfonyl analogues of β-lactams or cyclized compounds of taurine. Β-Sultams have thus been investigated from chemical and pharmacological points of view. A β-sultam is made up of a strained four-membered ring with three different hetero single C-N, C-S and N-S bonds. If a hetero bond is cleaved selectively and heterolytically, β-sultams may be used as synthetic equivalents of 2-aminoethyl cations, 2-aminoethane-sulfonyl cations or 2-sulfamoylethyl cations etc. Hetero bond cleavage in β-sultams is discussed.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00053514","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Laboratory of Pharmaceutical Chemistry, Gifu Pharmaceutical University"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"岐阜薬科大学"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1999-06-30"}],"displaytype":"detail","filename":"KJ00000073752.pdf","filesize":[{"value":"985.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://gifu-pu.repo.nii.ac.jp/record/11689/files/KJ00000073752.pdf"},"version_id":"9d963e03-ee7b-4e70-9a30-9cc7bfa38801"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<総説>β-スルタムのヘテロ結合の開裂反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<総説>β-スルタムのヘテロ結合の開裂反応"},{"subitem_title":"<Review>Hetero Bond Cleavage in β-Sultams","subitem_title_language":"en"}]},"item_type_id":"1","owner":"5","path":["195"],"pubdate":{"attribute_name":"公開日","attribute_value":"1999-06-30"},"publish_date":"1999-06-30","publish_status":"0","recid":"11689","relation_version_is_last":true,"title":["<総説>β-スルタムのヘテロ結合の開裂反応"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2023-06-19T09:05:43.133784+00:00"}