@article{oai:gifu-pu.repo.nii.ac.jp:00012604, author = {本多, 栄治 and 片岡, 貞 and ホンダ, エイジ and カタオカ, タダシ and HONDA, Eiji and KATAOKA, Tadashi}, journal = {岐阜藥科大學紀要, The annual proceedings of Gifu College of Pharmacy}, month = {Jun}, note = {P(論文), 活発な研究が行われているヘテロベンゼンのなかで,セレナベンゼンは未だ安定に単離されていなかったが,電子求引基によって安定化されたセレナベンゼンが,本研究で初めて空気中室温で安定に単離された。セレナベンゼンの反応を行い,化学的性質を解明するとともに,各種機器スペクトルデータ,X線結晶構造解析によりその構造を明らかにした。, The chemistry of heterobenzenes is one of the interesting research fields in heterocyclic chemistry and recently attention has been focused on them. Selenabenzenes with two electron-withdrawing groups (EWGs) at 2- and 6-positions 44a-c were synthesized from dihalides 25a, 25b and 25c' via 7 steps and isolated as stable compounds at room temperatwe. According to X-ray structual analysis of a benzoyl derivative 44c, the six membered ring containing a selenium atom was almost planar and the structure of the selenium atom was tetrahedral with four sp^3 hybridized orbitals.}, pages = {1--12}, title = {<総説>電子求引基で安定化されたセレナベンゼンの合成に関する研究}, volume = {51}, year = {2002} }