{"created":"2023-06-19T07:25:16.229918+00:00","id":12937,"links":{},"metadata":{"_buckets":{"deposit":"5bde283b-6185-4bbb-8fea-f9c8ada461eb"},"_deposit":{"created_by":4,"id":"12937","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"12937"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00012937","sets":["147:217"]},"author_link":["17983","17982","17979","17975","17980","17976","17978","17974","17973","17977","17984","17981"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"9","bibliographicPageStart":"1","bibliographicVolumeNumber":"60","bibliographic_titles":[{"bibliographic_title":"岐阜薬科大学紀要　"},{"bibliographic_title":"The annual proceedings of Gifu Pharmaceutical University","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"平島, 真一"}],"nameIdentifiers":[{"nameIdentifier":"17973","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"多田, 教浩"}],"nameIdentifiers":[{"nameIdentifier":"17974","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"三浦, 剛"}],"nameIdentifiers":[{"nameIdentifier":"17975","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊藤, 彰近"}],"nameIdentifiers":[{"nameIdentifier":"17976","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ヒラシマ, シンイチ"}],"nameIdentifiers":[{"nameIdentifier":"17977","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"タダ, ノリヒロ"}],"nameIdentifiers":[{"nameIdentifier":"17978","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ミウラ, ツヨシ"}],"nameIdentifiers":[{"nameIdentifier":"17979","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"イトウ, アキチカ"}],"nameIdentifiers":[{"nameIdentifier":"17980","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"HIRASHIMA, Shin-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17981","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TADA, Norihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17982","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"MIURA, Tsuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17983","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ITOH, Akichika","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17984","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"酸化反応は有機合成における最も重要な柱の一つである。しかしながら、従来の酸化反応は重金属を大量に使用しなければならない、廃棄物が大量に副生するなどの問題点を有しており、いわゆる“グリーンケミストリー”の概念に必ずしもそぐわないものがほとんどであった。一方、最近では安価で原子効率が高い分子状酸素を酸化剤として用いた触媒的酸化反応が報告されている。この方法は適当な触媒を用いた場合に、反応後に副生されるものが理論的に水のみであり、理想の酸化反応として注目を集めている。\n係る背景において、筆者らは分子状酸素を用いる酸化反応について研究を行い、紫外光照射下（<400 nm）、HBrやBr2のような触媒量の臭素源存在下、芳香環上メチル基やアルコール類から対応するカルボン酸への酸化反応の開発に成功した。また、臭素源として触媒量のMgBr2を用いることにより可視光照射下（>400 nm）でも同様の酸化反応が進行することも見出した。さらに、上記の光酸素酸化反応を連続するエステル化反応へ展開し、芳香環上メチル基から芳香族カルボン酸エステルへの効率的な直接一段階合成法を確立することにも成功した。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Oxidation is a very important transformation in organic synthesis; however, hitherto these methods usually involve the use of large quantities of heavy metals, which generate a large amount of waste, and are detrimental to the environment. On the other hand, recently, many researchers have reported catalytic oxidation processes with molecular oxygen, which generate little waste. Molecular oxygen has received a great deal of attention as an ideal oxidant, since it theoretically produces only water as the end product with a certain suitable catalyst is inexpensive and has higher atom efficiency than that of other oxidants.\nWith this perspective, we have studied the oxidation with molecular oxygen, and developed the oxidation of methyl aromatics and alcohols to the corresponding carboxylic groups in the presence of a catalytic amount of bromine sources such as aq. HBr and Br2 under UV irradiation (<400 nm). We have found that the same oxidations proceeded in the presence of a catalytic amount of MgBr2 as a bromine source under visible light (VIS) irradiation (>400 nm). Moreover, in developing the above-mentioned oxidation following esterification, we accomplished efficient direct aerobic photooxidative synthesis of aromatic methyl esters from methyl aromatics.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AA1258935X","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry, the University of Chicago"},{"subitem_text_language":"en","subitem_text_value":"Laboratory of Pharmaceutical Synthetic Chemistry, Gifu Pharmaceutical University"}]},"item_1_text_2":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_text_value":"総説"}]},"item_1_text_3":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Review"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"シカゴ大学 化学科"},{"subitem_text_value":"岐阜薬科大学創薬化学大講座合成薬品製造学研究室"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-07-29"}],"displaytype":"detail","filename":"光と酸素を活用する簡便な酸化プロセスの開発に関する研究.pdf","filesize":[{"value":"785.0 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"光と酸素を活用する簡便な酸化プロセスの開発に関する研究","url":"https://gifu-pu.repo.nii.ac.jp/record/12937/files/光と酸素を活用する簡便な酸化プロセスの開発に関する研究.pdf"},"version_id":"d64b363a-8ab3-48ed-81ea-06d40d943b95"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"酸素酸化","subitem_subject_scheme":"Other"},{"subitem_subject":"光酸化","subitem_subject_scheme":"Other"},{"subitem_subject":"臭素源","subitem_subject_scheme":"Other"},{"subitem_subject":"紫外光(UV)","subitem_subject_scheme":"Other"},{"subitem_subject":"可視光(VIS)","subitem_subject_scheme":"Other"},{"subitem_subject":"aerobic oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"photooxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"bromine sources","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ultraviolet light (UV)","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"visible light (VIS)","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"光と酸素を活用する簡便な酸化プロセスの開発に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光と酸素を活用する簡便な酸化プロセスの開発に関する研究"},{"subitem_title":"Study of a Facile Oxidation Process with Light and Molecular Oxygen","subitem_title_language":"en"}]},"item_type_id":"1","owner":"4","path":["217"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-07-29"},"publish_date":"2014-07-29","publish_status":"0","recid":"12937","relation_version_is_last":true,"title":["光と酸素を活用する簡便な酸化プロセスの開発に関する研究"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-06-19T09:02:22.859829+00:00"}