{"created":"2023-06-19T07:25:18.025136+00:00","id":12983,"links":{},"metadata":{"_buckets":{"deposit":"0a76d926-0613-443d-9db9-8bfc81060347"},"_deposit":{"created_by":4,"id":"12983","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"12983"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00012983","sets":["147:220"]},"author_link":["18140","18143","18134","18137","18141","18132","18136","18142","18138","18135","18139","18133"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"42","bibliographicPageStart":"33","bibliographicVolumeNumber":"63","bibliographic_titles":[{"bibliographic_title":"岐阜薬科大学紀要　"},{"bibliographic_title":"The annual proceedings of Gifu Pharmaceutical University","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"信田, 智哉"}],"nameIdentifiers":[{"nameIdentifier":"18132","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"多田, 教浩"}],"nameIdentifiers":[{"nameIdentifier":"18133","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"三浦, 剛"}],"nameIdentifiers":[{"nameIdentifier":"18134","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊藤, 彰近"}],"nameIdentifiers":[{"nameIdentifier":"18135","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ノブタ, トモヤ"}],"nameIdentifiers":[{"nameIdentifier":"18136","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"タダ, ノリヒロ"}],"nameIdentifiers":[{"nameIdentifier":"18137","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ミウラ, ツヨシ"}],"nameIdentifiers":[{"nameIdentifier":"18138","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"イトウ, アキチカ"}],"nameIdentifiers":[{"nameIdentifier":"18139","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"NOBUTA, Tomoya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18140","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TADA, Norihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18141","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"MIURA, Tsuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18142","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ITOH, Akichika","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"18143","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"酸化反応は有機合成上有用な反応であるが、従来の手法では毒性の高い重金属酸化剤や原子効率の低い複雑な有機\n分子が必要であった。一方、分子状酸素や過酸化水素を末端酸化剤とする手法は、原子効率が高く、廃棄物として理論上\n水のみを排出する、グリーンケミストリーの概念に合致した酸化法である。筆者らは最終酸化剤としての「過酸化水素」\nならびに「分子状酸素」を利用した環境負荷低減を指向した酸化反応の開発を行った。その結果、ハロゲンソース存在下、\nスチレン類の光酸素酸化により、対応するフェナシルハライド類を合成することに成功した。また、光酸素酸化反応の後\nに単体ヨウ素を触媒とする反応をワンポットで行うことにより、スチレン類からアセトフェノン類を、ベンジルアルコー\nル類からビスインドリルメタン類をそれぞれ合成することに成功した。さらに、単体ヨウ素存在下、酸化剤として過酸化\n水素或いは分子上酸素を用いることにより、三級アミン類と炭素求核剤の酸化的カップリング反応にも成功した。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Oxidation is one of the most important reactions in organic synthesis; however, classical methods require toxic heavy\nmetal reagents or complex organic molecules. On the other hand, oxidation using oxygen or hydrogen peroxide has received much\nattention in organic synthesis recently since these reagents are effective oxidants of larger atom efficiency and theoretically produce\nonly water as the end product. With this perspective, we have studied oxidation using oxygen or hydrogen peroxide as a terminal\noxidant. As a result, we found that styrenes can be oxidized to corresponding phenacylhalides under aerobic photo-oxidative\nconditions in the presence of halogen sources. We also developed one-pot synthesis of acetophenones and bis-indolylmethanes from\nstyrenes and benzylalcohols, which includes aerobic photo-oxidation followed by iodine catalyzed reaction, respectively.\nFurthermore, we developed a cross-dehydrogenative coupling reaction between tertiary amines and carbon nucleophiles using\nhydrogen peroxide or oxygen as a terminal oxidant in the presence of catalytic iodine.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AA1258935X","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Max Planck Institute of Colloids and Interfaces, Department of Biomolecular Systems"},{"subitem_text_language":"en","subitem_text_value":"Laboratory of Pharmaceutical Synthetic Chemistry, Gifu Pharmaceutical University"},{"subitem_text_language":"en","subitem_text_value":"Pharmaceutical Chemistry, Tokyo University of Pharmacy and Life Sciences"}]},"item_1_text_2":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_text_value":"総説"}]},"item_1_text_3":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Review"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"Max Planck Institute of Colloids and Interfaces, Department of Biomolecular Systems"},{"subitem_text_value":"岐阜薬科大学創薬化学大講座合成薬品製造学研究室"},{"subitem_text_value":"東京薬科大学薬学部薬化学教室"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-08-06"}],"displaytype":"detail","filename":"光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究","url":"https://gifu-pu.repo.nii.ac.jp/record/12983/files/光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究.pdf"},"version_id":"761985ad-9aea-41d1-ac92-ad4098e1d0b3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"酸素酸化","subitem_subject_scheme":"Other"},{"subitem_subject":"光酸化","subitem_subject_scheme":"Other"},{"subitem_subject":"過酸化水素","subitem_subject_scheme":"Other"},{"subitem_subject":"単体ヨウ素","subitem_subject_scheme":"Other"},{"subitem_subject":"脱水素型クロスカップリング","subitem_subject_scheme":"Other"},{"subitem_subject":"aerobic oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"photo oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogen peroxide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"iodine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"cross-dehydrogenative coupling","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究"},{"subitem_title":"Development of Oxidation Using Light and Oxygen, or Hydrogen Peroxide","subitem_title_language":"en"}]},"item_type_id":"1","owner":"4","path":["220"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-08-06"},"publish_date":"2014-08-06","publish_status":"0","recid":"12983","relation_version_is_last":true,"title":["光と酸素或いは過酸化水素を用いる酸化反応の開発に関する研究"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-06-19T09:01:07.444971+00:00"}