Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-​Trifluoroacetic Acid Complexes

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Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-Trifluoroacetic Acid Complexes

https://gifu-pu.repo.nii.ac.jp/records/13094

Item type		研究室原著論文(1)
公開日		2017-12-15
タイトル
	タイトル	Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-Trifluoroacetic Acid Complexes
	言語	en
言語
	言語	eng
キーワード
	言語	en
	主題Scheme	Other
	主題	iodosylbenzene
キーワード
	言語	en
	主題Scheme	Other
	主題	trifluoroacetic acid
キーワード
	言語	en
	主題Scheme	Other
	主題	pseudocyclic
キーワード
	言語	en
	主題Scheme	Other
	主題	coordination
キーワード
	言語	en
	主題Scheme	Other
	主題	oxidation
資源タイプ
	資源タイプ識別子	http://purl.org/coar/resource_type/c_6501
	資源タイプ	journal article
アクセス権
	アクセス権	metadata only access
	アクセス権URI	http://purl.org/coar/access_right/c_14cb
抄録
	値	An ortho-substituted ether-oxygen-coordinated pseudocyclic iodosylbenzene-trifluoroacetic acid (pcISB-TFA) complex was synthesized and characterized by X-ray crystallographic analysis. TFA suppresses the disproportionation by both coordination of the oxygen atom to the iodine (III) center through secondary bonding and hydrogen bonding to the oxygen anion. This bench-stable reagent is highly soluble in common organic solvents and reacts with various organic substrates under mild reaction conditions to give the corresponding products in good yields.
書誌情報		en : European Journal of Organic Chemistry 巻 2018, 号 4, p. 550-556, 発行日 2018-01-31
DOI
	値	org/10.1002/ejoc.201701521