{"created":"2023-06-19T07:25:21.040754+00:00","id":13094,"links":{},"metadata":{"_buckets":{"deposit":"2c36f808-d79a-49f3-8740-2f84d3f97e4f"},"_deposit":{"created_by":34,"id":"13094","owners":[34],"pid":{"revision_id":0,"type":"depid","value":"13094"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00013094","sets":["212:257:321"]},"author_link":["18345","18344","18343","18346","18342"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-01-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"556","bibliographicPageStart":"550","bibliographicVolumeNumber":"2018","bibliographic_titles":[{},{"bibliographic_title":"European Journal of Organic Chemistry","bibliographic_titleLang":"en"}]}]},"item_3_text_4":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_text_value":"org/10.1002/ejoc.201701521"}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"An ortho-substituted ether-oxygen-coordinated pseudocyclic iodosylbenzene-trifluoroacetic acid (pcISB-TFA) complex was synthesized and characterized by X-ray crystallographic analysis. TFA suppresses the disproportionation by both coordination of the oxygen atom to the iodine (III) center through secondary bonding and hydrogen bonding to the oxygen anion. This bench-stable reagent is highly soluble in common organic solvents and reacts with various organic substrates under mild reaction conditions to give the corresponding products in good yields."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"iodosylbenzene","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"trifluoroacetic acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"pseudocyclic","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"coordination","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-​Trifluoroacetic Acid Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-​Trifluoroacetic Acid Complexes","subitem_title_language":"en"}]},"item_type_id":"3","owner":"34","path":["321"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-12-15"},"publish_date":"2017-12-15","publish_status":"0","recid":"13094","relation_version_is_last":true,"title":["Synthesis, Characterization, and Reaction of a Both Inter- and Intramolecularly Coordinated Pseudocyclic Iodosylbenzene-​Trifluoroacetic Acid Complexes"],"weko_creator_id":"34","weko_shared_id":-1},"updated":"2023-06-19T08:58:47.134403+00:00"}