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Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen
https://gifu-pu.repo.nii.ac.jp/records/13149
https://gifu-pu.repo.nii.ac.jp/records/1314973092782-ee7a-4569-8a24-0e3fc928d072
| Item type | 研究室原著論文(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-06-19 | |||||
| タイトル | ||||||
| タイトル | Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | dextran | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | electron spin resonance (ESR) | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | glycogen | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | mechanoradical | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | polysaccharide | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 抄録 | ||||||
| 値 | A detailed electron spin resonance (ESR) analysis of mechanically induced free radicals (mechanoradicals) formation of glucosebased polysaccharides, dextran (Dx) and glycogen (Gly) was performed in comparison with amylose mechanoradicals. The ESR spectra of the samples mechanically fractured at room temperature were multicomponent. The radical concentration of Dx and Gly mechanoradicals gradually decreased during vibratory milling after reaching the maximum value. Although the molecular weight of Dx or the particle diameter of Gly steeply diminished until reaching the each maximum value of radical concentration, after that the molecular weight or the particle diameter slowly decreased. These results suggested that Dx and Gly mechanoradicals might be more unstable than amylose radicals possessing an intramolecular helical structure due to the branched structure. | |||||
| 書誌情報 |
en : Beilstein J. Org. Chem. 巻 13, p. 1174-1183, 発行日 2017-06-19 |
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| DOI | ||||||
| 値 | 10.3762/bjoc.13.116 | |||||
