{"created":"2023-06-19T07:25:33.228921+00:00","id":13445,"links":{},"metadata":{"_buckets":{"deposit":"80eac637-5516-46fd-beb8-3e9eb4624a78"},"_deposit":{"created_by":34,"id":"13445","owners":[34],"pid":{"revision_id":0,"type":"depid","value":"13445"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00013445","sets":["212:257:321"]},"author_link":["21731","21730","21733","21732","21734"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-02-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"1102","bibliographicPageStart":"1098","bibliographicVolumeNumber":"21","bibliographic_titles":[{},{"bibliographic_title":"Organic Letters","bibliographic_titleLang":"en"}]}]},"item_3_text_4":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_text_value":"10.1021/acs.orglett.9b00005"}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"The synthesis of a cryst. ethynyl-1,2-benziodoxol-3(1H)-one (EBX)-acetonitrile complex is described.  EBX has been widely used as an active species for a variety of reactions; however, its high instability has so far prevented its isolation.  The EBX-acetonitrile is self-assembled into a double-layered honeycomb structure through weak hypervalent iodine secondary interactions and hydrogen bonding.  The N-ethynylation of a variety of sulfonamides using the EBX-acetonitrile complex as a substrate under mild conditions is also described."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, Characterization, and Reactivity of an Ethynyl Benziodoxolone (EBX)–Acetonitrile Complex","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, Characterization, and Reactivity of an Ethynyl Benziodoxolone (EBX)–Acetonitrile Complex","subitem_title_language":"en"}]},"item_type_id":"3","owner":"34","path":["321"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-03-04"},"publish_date":"2019-03-04","publish_status":"0","recid":"13445","relation_version_is_last":true,"title":["Synthesis, Characterization, and Reactivity of an Ethynyl Benziodoxolone (EBX)–Acetonitrile Complex"],"weko_creator_id":"34","weko_shared_id":-1},"updated":"2023-06-19T08:48:14.704073+00:00"}