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Atom‐Transfer Radical Addition Photocatalysis Using a Heteroleptic Copper Complex
https://gifu-pu.repo.nii.ac.jp/records/13449
https://gifu-pu.repo.nii.ac.jp/records/13449d6e249b2-f080-4eb0-8d62-bb9fb5839c81
| Item type | 研究室原著論文(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-03-04 | |||||
| タイトル | ||||||
| タイトル | Atom‐Transfer Radical Addition Photocatalysis Using a Heteroleptic Copper Complex | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 抄録 | ||||||
| 値 | Herein, we describe a photocatalyzed atom-transfer radical addn. (ATRA) reaction using a heteroleptic copper(I) complex bearing a bipyridyl-based NN ligand and a 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) based PP ligand. The selected heteroleptic complex was [Cu(BINAP)(cup)](PF6), which was used because of its intense absorption in the visible region and its long excited-state lifetime. The reported copper photocatalyzed reactions of olefins with carbon tetrabromide afford the products in moderate-to-excellent yields under irradn. with a 3 W, 400 nm light emitting diode (LED). | |||||
| 書誌情報 |
en : Asian Journal of Organic Chemistry 巻 7, 号 12, p. 2435-2438, 発行日 2018-12-13 |
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| DOI | ||||||
| 値 | 10.1002/ajoc.201800533 | |||||
