{"created":"2023-06-19T07:26:01+00:00","id":14232,"links":{},"metadata":{"_buckets":{"deposit":"9b7c59ba-9c52-4969-9fa4-c54389ebb988"},"_deposit":{"created_by":54,"id":"14232","owners":[54],"pid":{"revision_id":0,"type":"depid","value":"14232"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00014232","sets":["212:258:318"]},"author_link":["32684","32676","32677","32682","32681","32678","32683","32679","32680"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1222","bibliographicPageStart":"1209","bibliographicVolumeNumber":"10","bibliographic_titles":[{},{"bibliographic_title":"Catalysts","bibliographic_titleLang":"en"}]}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"The Suzuki–Miyaura coupling reaction is one of the most widely utilized C–C bond forming methods to create (hetero)biaryl scaffolds. The continuous-flow reaction using heterogeneous catalyst-packed cartridges is a practical and efficient synthetic method to replace batch-type reactions. A continuous-flow ligand-free Suzuki–Miyaura coupling reaction of (hetero)aryl iodides, bromides, and chlorides with (hetero)aryl boronic acids was developed using cartridges packed with spherical resin (tertiary amine-based chelate resin: WA30)-supported palladium catalysts (7% Pd/WA30). The void space in the cartridge caused by the spherical catalyst structures enables the smooth flow of a homogeneously dissolved reaction solution that consists of a mixture of organic and aqueous solvents and is delivered by the use of a single syringe pump. Clogging or serious backpressure was not observed."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Development of Facile and Simple Processes for the Heterogeneous Pd-Catalyzed Ligand-Free Continuous-Flow Suzuki–Miyaura Coupling","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Development of Facile and Simple Processes for the Heterogeneous Pd-Catalyzed Ligand-Free Continuous-Flow Suzuki–Miyaura Coupling","subitem_title_language":"en"}]},"item_type_id":"3","owner":"54","path":["318"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-03"},"publish_date":"2021-03-03","publish_status":"0","recid":"14232","relation_version_is_last":true,"title":["Development of Facile and Simple Processes for the Heterogeneous Pd-Catalyzed Ligand-Free Continuous-Flow Suzuki–Miyaura Coupling"],"weko_creator_id":"54","weko_shared_id":-1},"updated":"2023-06-19T07:44:49.175562+00:00"}