{"created":"2023-06-19T07:26:01.042278+00:00","id":14233,"links":{},"metadata":{"_buckets":{"deposit":"986b7b82-fea3-4bf4-8a61-f96cc0a7d1b6"},"_deposit":{"created_by":54,"id":"14233","owners":[54],"pid":{"revision_id":0,"type":"depid","value":"14233"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00014233","sets":["212:258:318"]},"author_link":["32690","32695","32686","32688","32692","32694","32691","32697","32698","32687","32689","32693","32685","32696"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"6367","bibliographicPageStart":"6359","bibliographicVolumeNumber":"10","bibliographic_titles":[{},{"bibliographic_title":"Catalysis Science & Technology","bibliographic_titleLang":"en"}]}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"Two different types of palladium catalysts supported on dual-pore monolithic silica beads [5% Pd/SM and 0.25% Pd/SM(sc)] for chemoselective hydrogenation were developed. Alkyne, alkene, azide, and nitro functionalities and the aromatic N-Cbz protecting group were chemoselectively hydrogenated using 5% Pd/SM. On the other hand, 0.25% Pd/SM(sc) showed unique and higher hydrogenation catalyst activity toward a wide variety of reducible functionalities. Furthermore, the catalyst activities of both 5% Pd/SM and 0.25% Pd/SM(sc) under flow hydrogenation conditions were also evaluated. A pre-packed 5% Pd/SM cartridge could be used continuously for at least 72 h without any loss of catalyst activity. The 0.2% Pd/SM(sc) catalyst prepacked in a cartridge showed high catalyst activity for the flow hydrogenation of trisubstituted alkenes under mild reaction conditions."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Pd catalysts supported on dual-pore monolithic silica beads for chemoselective hydrogenation under batch and flow reaction conditions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Pd catalysts supported on dual-pore monolithic silica beads for chemoselective hydrogenation under batch and flow reaction conditions","subitem_title_language":"en"}]},"item_type_id":"3","owner":"54","path":["318"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-03"},"publish_date":"2021-03-03","publish_status":"0","recid":"14233","relation_version_is_last":true,"title":["Pd catalysts supported on dual-pore monolithic silica beads for chemoselective hydrogenation under batch and flow reaction conditions"],"weko_creator_id":"54","weko_shared_id":-1},"updated":"2023-06-19T07:44:54.425660+00:00"}