{"created":"2023-06-19T07:26:01.256275+00:00","id":14238,"links":{},"metadata":{"_buckets":{"deposit":"4358e8a4-532d-44b4-a808-16ef27f26083"},"_deposit":{"created_by":54,"id":"14238","owners":[54],"pid":{"revision_id":0,"type":"depid","value":"14238"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00014238","sets":["212:258:318"]},"author_link":["32722","32727","32724","32726","32728","32725","32720","32723","32721"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-01-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1351","bibliographicPageStart":"1344","bibliographicVolumeNumber":"19","bibliographic_titles":[{},{"bibliographic_title":"Organic & Biomolecular Chemistry","bibliographic_titleLang":"en"}]}]},"item_3_text_4":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_text_value":"10.1039/D0OB02518F"}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"Facilitated by the dual role of Ceric Ammonium Nitrate (CAN), herein we report a cost-effective approach for the cyanation of aryl iodides/bromides with CAN–DMF as an addition to the existing pool of combined cyanation sources. In addition to being an oxidant, CAN acts as a source of nitrogen in our protocol. The reaction is catalyzed by a readily available Cu(II) salt and the ability of CAN to generate ammonia in the reaction medium is utilized to eliminate the additional requirement of a nitrogen source, ligand, additive or toxic reagents. The mechanistic study suggests an evolution of CN− leading to the synthesis of a variety of aryl nitriles in moderate to good yields. The proposed mechanism is supported by a series of control reactions and labeling experiments."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Revisiting the synthesis of aryl nitriles: a pivotal role of CAN","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Revisiting the synthesis of aryl nitriles: a pivotal role of CAN","subitem_title_language":"en"}]},"item_type_id":"3","owner":"54","path":["318"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-03"},"publish_date":"2021-03-03","publish_status":"0","recid":"14238","relation_version_is_last":true,"title":["Revisiting the synthesis of aryl nitriles: a pivotal role of CAN"],"weko_creator_id":"54","weko_shared_id":-1},"updated":"2023-06-19T07:44:53.731189+00:00"}