{"created":"2023-06-19T07:26:07.024396+00:00","id":14389,"links":{},"metadata":{"_buckets":{"deposit":"e9bf9ac2-97be-4ac5-8044-f69494580274"},"_deposit":{"created_by":16,"id":"14389","owners":[16],"pid":{"revision_id":0,"type":"depid","value":"14389"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00014389","sets":["212:257:321"]},"author_link":["33612","33611","33614","33613"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"153251","bibliographicVolumeNumber":"77","bibliographic_titles":[{},{"bibliographic_title":"Tetrahedron Letters","bibliographic_titleLang":"en"}]}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"In this study, direct C-N bond formation was achieved via the reaction of a di-Me methylmalonate with various amines in the presence of mol. iodine to produce α-aminocarbonyl compounds This versatile methodol. of the α-amination of a carbonyl-containing compound involves the in situ iodination of the di-Me methylmalonate, thus promoting the formation of its enolate isomer, which then facilitates its nucleophilic substitution reaction with an amine. This strategy is highly practical and can be used in industry due to its requirement of only readily available reagents without any pre-preparation of the amines and other substrates."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Iodine-mediated direct α-amination of dimethyl methylmalonate using non-protected amines","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Iodine-mediated direct α-amination of dimethyl methylmalonate using non-protected amines"},{"subitem_title":"Iodine-mediated direct α-amination of dimethyl methylmalonate using non-protected amines","subitem_title_language":"en"}]},"item_type_id":"3","owner":"16","path":["321"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-03-02"},"publish_date":"2022-03-02","publish_status":"0","recid":"14389","relation_version_is_last":true,"title":["Iodine-mediated direct α-amination of dimethyl methylmalonate using non-protected amines"],"weko_creator_id":"16","weko_shared_id":-1},"updated":"2023-06-19T07:43:17.680010+00:00"}