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Synthesis of 4-imidazolidinones from diamides and ethynyl benziodoxolones vis double michael addition: ethynyl benziodoxolones as electrophilic ynol synthons
https://gifu-pu.repo.nii.ac.jp/records/14397
https://gifu-pu.repo.nii.ac.jp/records/143976ee60042-6c77-45dd-aac1-90b4be17af84
| Item type | 研究室原著論文(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2022-03-02 | |||||
| タイトル | ||||||
| タイトル | Synthesis of 4-imidazolidinones from diamides and ethynyl benziodoxolones vis double michael addition: ethynyl benziodoxolones as electrophilic ynol synthons | |||||
| タイトル | ||||||
| タイトル | Synthesis of 4-imidazolidinones from diamides and ethynyl benziodoxolones vis double michael addition: ethynyl benziodoxolones as electrophilic ynol synthons | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 抄録 | ||||||
| 値 | The moiety of 4-imidazolidinone is an important structural motif in organic synthesis and medicinal chem. We present the synthesis of 4-imidazolidinones from various diamides with ethynyl benziodoxolones through double Michael addition, which is an unprecedented reaction mode for hypervalent alkynyl iodine compounds cis-2,5-disubstituted 4-imidazolidinones were diastereoselectively synthesized from amino-acid-derived diamides. Having derivatized the 4-imidazolidinones, several control experiments and d. functional theory calculations were conducted to realize mechanistic insight. | |||||
| 書誌情報 |
ChemRxiv en : ChemRxiv p. 1-6, 発行日 2022 |
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