{"created":"2023-06-19T07:26:07.364522+00:00","id":14399,"links":{},"metadata":{"_buckets":{"deposit":"e84e40cd-085c-43bb-8aed-8f96dac065b8"},"_deposit":{"created_by":16,"id":"14399","owners":[16],"pid":{"revision_id":0,"type":"depid","value":"14399"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00014399","sets":["212:257:321"]},"author_link":["18232","33664","33665","18304"],"item_3_biblio_info_3":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"801","bibliographicPageStart":"796","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"Chemical & Pharmaceutical Bulletin"},{"bibliographic_title":"Chemical & Pharmaceutical Bulletin","bibliographic_titleLang":"en"}]}]},"item_3_textarea_2":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_textarea_value":"In this study, the atom transfer radical addition (ATRA) reaction of olefins RCH=CH2 (R = Bn, 3-methoxy-2-(methoxycarbonyl)-3-oxopropyl, hydroxymethyl, etc.) using bromomalonates R1C(C(O)R2)2Br (R1 = H, Me, n-Pr, 2-cyanoethyl; R2 = OMe, OEt, Ph, t-Bu) as halogen-bonding donors was developed. Using 4-phenylpyridine as the halogen-bonding acceptor, the desired reaction proceeded well under external irradiation of 380 nm light to furnish the corresponding ATRA reaction products RCH(Br)CH2C(C(O)R2)2R1. The ATRA reaction was effective in generating the corresponding products for a variety of olefins. Furthermore, the ATRA reaction was applicable to bulky ketones, substrates, and malonate esters. The intermediates of the reaction were identified and a plausible reaction mechanism was proposed."}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Photoinduced atom transfer radical addition reaction of olefins with α-bromo carbonyls","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Photoinduced atom transfer radical addition reaction of olefins with α-bromo carbonyls"},{"subitem_title":"Photoinduced atom transfer radical addition reaction of olefins with α-bromo carbonyls","subitem_title_language":"en"}]},"item_type_id":"3","owner":"16","path":["321"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-03-02"},"publish_date":"2022-03-02","publish_status":"0","recid":"14399","relation_version_is_last":true,"title":["Photoinduced atom transfer radical addition reaction of olefins with α-bromo carbonyls"],"weko_creator_id":"16","weko_shared_id":-1},"updated":"2023-06-19T07:43:14.498401+00:00"}