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Platinum on carbon-catalysed site-selective H–D exchange reaction of allylic alcohols using alkyl amines as a hydrogen source
https://gifu-pu.repo.nii.ac.jp/records/14713
https://gifu-pu.repo.nii.ac.jp/records/147137d2b2e08-9a78-4100-9240-49fcf50bf9a1
| Item type | 研究室原著論文(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2023-03-08 | |||||
| タイトル | ||||||
| タイトル | Platinum on carbon-catalysed site-selective H–D exchange reaction of allylic alcohols using alkyl amines as a hydrogen source | |||||
| タイトル | ||||||
| タイトル | Platinum on carbon-catalysed site-selective H–D exchange reaction of allylic alcohols using alkyl amines as a hydrogen source | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 抄録 | ||||||
| 値 | We developed a platinum on carbon-catalysed deuteration reaction of tert-allylic alcohols using deuterium oxide as a deuterium source. Amylamine was dehydrogenated by platinum on carbon to generate an appropriate amount of hydrogen gas, which efficiently promoted the H–D exchange reaction. Various allylic alcohols were site-selectively deuterated with good to excellent deuterium contents without hydrogenation of the alkene functionality. The obtained deuterium-labelled allylic alcohols were further transformed into various deuterium-labelled building blocks without degradation of the original deuterium content. | |||||
| 書誌情報 |
en : Organic Chemistry Frontiers 巻 9, 号 7, p. 1986-1991, 発行日 2022 |
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| DOI | ||||||
| 値 | 10.1039/D2QO00177B | |||||
