@article{oai:gifu-pu.repo.nii.ac.jp:00008093, author = {葛谷, 昌之 and クズヤ, マサユキ and KUZUYA, MASAYUKI}, journal = {岐阜藥科大學紀要, The annual proceedings of Gifu College of Pharmacy}, month = {Jun}, note = {P(論文), 有機気体のプラズマプロセシングにおいては, ユニークな重合薄膜を生成するプラズマ重合と共に, プラズマ開始重合と称されるビニルモノマーの重合をプラズマによって誘起させる高分子合成の新技術がある。現在まで本重合法は多くの特異現象を示すことが報告されており, 様々な興味ある応用も試みられて来ているが, 重合原理を含め不明瞭な点が多く残されている。本稿では, 筆者らのプラズマ開始重合の重合機構解明に端を発した研究から, 本重合が示す様々な特異現象を包括して説明出来る重合原理と, その原理から案出された新プラズマ開始重合について概説する。, In plasma-processing using organic vapors, two types of polymerizations are known; plasma-state polymerization which forms a unique plasma-polymerized thin film, and a novel method for plasma-induced radical chain polymerization of vinyl monomers which is referred to as plasma-initiated polymerization. Although a variety of unusual reaction features and interesting applications have so far been reported in the plasma-initiated polymerization, much remains to be seen including the polymerization mechanism. In this review, we delineate the mechanism which we believe can clarify ambiguities posed in plasma-initiated polymerization, and a novel polymerization technique derived from such studies for elucidation of the mechanism which we refer to as a new plasma-initiated polymerization.}, pages = {11--25}, title = {<総説>新プラズマ開始重合}, volume = {36}, year = {1987} }