{"created":"2023-06-19T07:23:43.841166+00:00","id":8469,"links":{},"metadata":{"_buckets":{"deposit":"80b5db49-b98c-44db-a85e-b86bd3efc63f"},"_deposit":{"created_by":5,"id":"8469","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"8469"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00008469","sets":["147:186"]},"author_link":["13474","13476","13475"],"item_1_alternative_title_5":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_alternative_title":"〓"}]},"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1990-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"28","bibliographicPageStart":"16","bibliographicVolumeNumber":"39","bibliographic_titles":[{"bibliographic_title":"岐阜藥科大學紀要"},{"bibliographic_title":"The annual proceedings of Gifu College of Pharmacy","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"落合, 正仁"}],"nameIdentifiers":[{"nameIdentifier":"13474","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"オチアイ, マサヒト"}],"nameIdentifiers":[{"nameIdentifier":"13475","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"OCHIAI, MASAHITO","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"13476","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"スズ原子とヘテロ原子との間の分子内超原子価相互作用により, シス-1,3-二置換シクロヘキサン類を通常は不安定で取り得ないdiaxial配座に固定化し, 反応の立体化学の制御を行なうという新しい概念に基づいた二重結合のオスミウム酸化反応について紹介する。また, スタンニル基の水酸基への立体特異的変換反応, 及びスズ原子を立体制御因子とする環状γ-スタンニルアルコール類の酸化的環開裂反応についても言及する。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Fixation of the molecular geometry of cis-1,3-disubstituted cyclohexanes to the 1 , 3-diaxial conformer through intramolecular hypervalent interaction between tin and heteroatoms makes possible a highly stereoselective osmylation of double bonds. Stereospecific conversion of stannyl groups into hydroxyl groups and tin-directed oxidative ring opening of γ-stannyl alcohols are also presented.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00053514","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Synthetic Organic Chemistry, Gifu Pharmaceutical University"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"岐阜薬科大学"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1990-06-30"}],"displaytype":"detail","filename":"KJ00000072395.pdf","filesize":[{"value":"758.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://gifu-pu.repo.nii.ac.jp/record/8469/files/KJ00000072395.pdf"},"version_id":"25b602ae-ca64-4a19-a9f9-16cfe5e123a3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<総説>有機スズ化合物による反応の高度立体制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<総説>有機スズ化合物による反応の高度立体制御"},{"subitem_title":"<Review>Highly Stereoselective Reaction Utilizing Organotin Compounds","subitem_title_language":"en"}]},"item_type_id":"1","owner":"5","path":["186"],"pubdate":{"attribute_name":"公開日","attribute_value":"1990-06-30"},"publish_date":"1990-06-30","publish_status":"0","recid":"8469","relation_version_is_last":true,"title":["<総説>有機スズ化合物による反応の高度立体制御"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2023-06-19T09:07:21.530610+00:00"}