{"created":"2023-06-19T07:23:58.858767+00:00","id":9080,"links":{},"metadata":{"_buckets":{"deposit":"b3345989-93f8-475b-8f28-e9edab691b41"},"_deposit":{"created_by":5,"id":"9080","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"9080"},"status":"published"},"_oai":{"id":"oai:gifu-pu.repo.nii.ac.jp:00009080","sets":["147:188"]},"author_link":["13081","24503","25099","4538","25094","25100","25098","13080","25095","25097","25096","23855"],"item_1_alternative_title_5":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_alternative_title":"〓"}]},"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1992-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"29","bibliographicPageStart":"23","bibliographicVolumeNumber":"41","bibliographic_titles":[{"bibliographic_title":"岐阜藥科大學紀要"},{"bibliographic_title":"The annual proceedings of Gifu College of Pharmacy","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 章公"}],"nameIdentifiers":[{"nameIdentifier":"25094","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"桝井, 泰司"}],"nameIdentifiers":[{"nameIdentifier":"25095","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"近藤, 伸一"}],"nameIdentifiers":[{"nameIdentifier":"25096","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"葛谷, 昌之"}],"nameIdentifiers":[{"nameIdentifier":"13080","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ノグチ, アキヒロ"}],"nameIdentifiers":[{"nameIdentifier":"25097","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"マスイ, ヤスシ"}],"nameIdentifiers":[{"nameIdentifier":"25098","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"コンドウ, シンイチ"}],"nameIdentifiers":[{"nameIdentifier":"25099","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"クズヤ, マサユキ"}],"nameIdentifiers":[{"nameIdentifier":"13081","nameIdentifierScheme":"WEKO"}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"NOGUCHI, AKIHIRO","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"24503","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"MASUI, YASUSHI","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"25100","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"KONDO, SHIN-ICHI","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"23855","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"KUZUYA, MASAYUKI","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4538","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"メタクリル酸(MAA)とそのn-アルキルエステル類(RMA)との共重合反応性を調べた結果, ベンゼン中の反応においてRMAのアルキル鎖の増長に伴うモノマー反応性比の大きな変化が認められたが, カルボソ酸中の反応においてはその変化は僅かであった。モノマー反応性比に対するアルキル鎖長の影響およびその溶媒効果の特徴, さらに重合成長反応性に対する水素結合の影響についての分子軌道計算結果を用いた摂動エネルギーによる評価より, モノマー反応性比に対するn-アルキル鎖の立体的影響は小さいこと, また, 実験結果におけるモノマー反応性比の変化は主として反応溶液中におけるMAAの水素結合会合平衡の影響によることが示された。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"The effect of the alkyl group on copolymerization of methacrylic acid(MAA)with its n-alkyl esters (RMA) was investigated. The monomer reactivity ratios largely varied with alkyl group length in reactions in benzene. This effect was not so great in reactions in carboxylic acids. The steric effects of alkyl groups on copolymerization would thus appear slight and variations in the reactivity ratio to possibly be due to variations in the hydrogen-bonding equilibria of MAA. The effects of the hydrogen bond on propagation reactivity were also discussed by perturbation energy based on quantum chemical calculations.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00053514","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University/Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University/Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University/Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"岐阜薬科大学/岐阜薬科大学/岐阜薬科大学/岐阜薬科大学"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1992-06-30"}],"displaytype":"detail","filename":"KJ00000072716.pdf","filesize":[{"value":"434.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://gifu-pu.repo.nii.ac.jp/record/9080/files/KJ00000072716.pdf"},"version_id":"8b359887-f9ec-4eec-978c-10bc04e638df"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<一般論文>メタクリル酸とそのn-アルキルエステル類との共重合反応性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<一般論文>メタクリル酸とそのn-アルキルエステル類との共重合反応性"},{"subitem_title":"<Regular Article>Copolymerization Reactivity of Methacrylic Acid with Its n-Alkyl Esters","subitem_title_language":"en"}]},"item_type_id":"1","owner":"5","path":["188"],"pubdate":{"attribute_name":"公開日","attribute_value":"1992-06-30"},"publish_date":"1992-06-30","publish_status":"0","recid":"9080","relation_version_is_last":true,"title":["<一般論文>メタクリル酸とそのn-アルキルエステル類との共重合反応性"],"weko_creator_id":"5","weko_shared_id":5},"updated":"2023-06-19T08:21:27.127476+00:00"}