{"_buckets": {"deposit": "59852dfc-9187-4426-a6ea-0e24fb5f90bb"}, "_deposit": {"created_by": 5, "id": "9361", "owners": [5], "pid": {"revision_id": 0, "type": "depid", "value": "9361"}, "status": "published"}, "_oai": {"id": "oai:gifu-pu.repo.nii.ac.jp:00009361", "sets": ["189"]}, "author_link": ["14369", "14368", "14367"], "item_1_alternative_title_5": {"attribute_name": "論文名よみ", "attribute_value_mlt": [{"subitem_alternative_title": "〓"}]}, "item_1_biblio_info_14": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1993-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "14", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "42", "bibliographic_titles": [{"bibliographic_title": "岐阜藥科大學紀要"}, {"bibliographic_title": "The annual proceedings of Gifu College of Pharmacy", "bibliographic_titleLang": "en"}]}]}, "item_1_creator_6": {"attribute_name": "著者名(日)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "井上, 謙一郎"}], "nameIdentifiers": [{"nameIdentifier": "14367", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_7": {"attribute_name": "著者名よみ", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "イノウエ, ケンイチロウ"}], "nameIdentifiers": [{"nameIdentifier": "14368", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_8": {"attribute_name": "著者名(英)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "INOUE, KENICHIRO", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14369", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_description_1": {"attribute_name": "ページ属性", "attribute_value_mlt": [{"subitem_description": "P(論文)", "subitem_description_type": "Other"}]}, "item_1_description_11": {"attribute_name": "抄録(日)", "attribute_value_mlt": [{"subitem_description": "Genipa americanaの果実のイリドイド成分であるgenipinは酸素存在下アミノ酸と容易に反応し青色色素を生成する。この色素は食用色素として利用されているが, 高分子混合物でその構造は明らかにされていない。この青色色素の構造解析と生成機構解明のための基礎研究として, 酸素遮断下genipinをmethylamineと反応させたところ, 9種の赤褐色物質を与えた。さらに酸素存在下で反応を継続すると青色色素を生成した。ここでは, まずこれら赤褐色物質の構造と分光学的特性について述べ, 次にこれらの生成機構について考察した。", "subitem_description_type": "Other"}]}, "item_1_description_12": {"attribute_name": "抄録(英)", "attribute_value_mlt": [{"subitem_description": "Genipin, an iridoid constituent of Genipa americana, readily reacts with amino acids in the presence of oxygen to give a mixture of polymeric blue pigments whose structures are not determined. In the basic studies to elucidate the structure and formation mechnism of blue pigments, the reaction of genipin with methylamine in the absence of oxygen yielded 9 red compounds leading to blue pigments. In this article, the structures and spectroscopic properties of these red compounds were described. The formation mechnism also was discussed.", "subitem_description_type": "Other"}]}, "item_1_source_id_13": {"attribute_name": "雑誌書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00053514", "subitem_source_identifier_type": "NCID"}]}, "item_1_text_10": {"attribute_name": "著者所属(英)", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "Laboratory of Pharmacognosy, Gifu Pharmaceutical University"}]}, "item_1_text_9": {"attribute_name": "著者所属(日)", "attribute_value_mlt": [{"subitem_text_value": "岐阜薬科大学"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "1993-06-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KJ00000072854.pdf", "filesize": [{"value": "811.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 811200.0, "url": {"url": "https://gifu-pu.repo.nii.ac.jp/record/9361/files/KJ00000072854.pdf"}, "version_id": "dd26360a-c5ad-4be9-a9be-6b76493364f2"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "\u003c総説\u003ePseudoazulene骨格を有する天然由来青色色素について", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "\u003c総説\u003ePseudoazulene骨格を有する天然由来青色色素について"}, {"subitem_title": "\u003cReview\u003eBlue Pseudoazulene-Skeleton Pigments of Natural Origin", "subitem_title_language": "en"}]}, "item_type_id": "1", "owner": "5", "path": ["189"], "permalink_uri": "https://gifu-pu.repo.nii.ac.jp/records/9361", "pubdate": {"attribute_name": "公開日", "attribute_value": "1993-06-30"}, "publish_date": "1993-06-30", "publish_status": "0", "recid": "9361", "relation": {}, "relation_version_is_last": true, "title": ["\u003c総説\u003ePseudoazulene骨格を有する天然由来青色色素について"], "weko_shared_id": -1}