{"_buckets": {"deposit": "a953b99d-170e-480f-b919-8da38e0dd18b"}, "_deposit": {"created_by": 5, "id": "11237", "owners": [5], "pid": {"revision_id": 0, "type": "depid", "value": "11237"}, "status": "published"}, "_oai": {"id": "oai:gifu-pu.repo.nii.ac.jp:00011237", "sets": ["194"]}, "author_link": ["13472", "7578", "8173", "17145", "17772", "21232", "22127", "23647", "17769", "21402", "8803", "23648", "21231", "17747", "22164", "13471", "22123", "17144"], "item_1_alternative_title_5": {"attribute_name": "論文名よみ", "attribute_value_mlt": [{"subitem_alternative_title": "〓"}]}, "item_1_biblio_info_14": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1998-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "53", "bibliographicPageStart": "49", "bibliographicVolumeNumber": "47", "bibliographic_titles": [{"bibliographic_title": "岐阜藥科大學紀要"}, {"bibliographic_title": "The annual proceedings of Gifu College of Pharmacy", "bibliographic_titleLang": "en"}]}]}, "item_1_creator_6": {"attribute_name": "著者名(日)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "奥村, 典子"}], "nameIdentifiers": [{"nameIdentifier": "17144", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "江坂, 幸宏"}], "nameIdentifiers": [{"nameIdentifier": "17769", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "瀬戸, 邦匡"}], "nameIdentifiers": [{"nameIdentifier": "23647", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "後藤, 正志"}], "nameIdentifiers": [{"nameIdentifier": "13471", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "河合, 聡"}], "nameIdentifiers": [{"nameIdentifier": "21231", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "宇野, 文二"}], "nameIdentifiers": [{"nameIdentifier": "17747", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_7": {"attribute_name": "著者名よみ", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "オクムラ, ノリコ"}], "nameIdentifiers": [{"nameIdentifier": "17145", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "エサカ, ユキヒロ"}], "nameIdentifiers": [{"nameIdentifier": "17772", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "セト, クニマサ"}], "nameIdentifiers": [{"nameIdentifier": "23648", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ゴトウ, マサシ"}], "nameIdentifiers": [{"nameIdentifier": "13472", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "カワイ, サトシ"}], "nameIdentifiers": [{"nameIdentifier": "21232", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ウノ, ブンジ"}], "nameIdentifiers": [{"nameIdentifier": "22123", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_8": {"attribute_name": "著者名(英)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "OKUMURA, Noriko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8173", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ESAKA, Yukihiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "7578", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "SETO, Kunimasa", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "22164", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "GOTO, Masashi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8803", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "KAWAI, Satoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "22127", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "UNO, Bunji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "21402", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_description_1": {"attribute_name": "ページ属性", "attribute_value_mlt": [{"subitem_description": "P(論文)", "subitem_description_type": "Other"}]}, "item_1_description_11": {"attribute_name": "抄録(日)", "attribute_value_mlt": [{"subitem_description": "日本薬局方収載の医薬品定量法であるFajans法の滴定終点を明瞭にするために,その改良法を開発した。Fajans法に用いる指示薬フルオレセインナトリウムの共役酸フルオレセインのpK_a値は分光学的方法により6.67と求められ,この指示薬は被滴定液中ではほとんど解離していないことが分かった。その結果,局方収載の方法ではアニオン性吸着指示薬の効果が小さく,明瞭な終点指示ができにくいものと考えられた。そこで,種々の緩衝液を用いて終点指示の鋭敏さとその精度を検討した結果,炭酸緩衝液が最も適することが分かった。以上述べたごとく,被滴定液に炭酸水素ナトリウム(初期濃度を約0.01mol/Lとする)を加える簡便な改良Fajans法を開発した。なお,この方法で得られた結果は,既存のMohr法で得られた結果とよく一致した。", "subitem_description_type": "Other"}]}, "item_1_description_12": {"attribute_name": "抄録(英)", "attribute_value_mlt": [{"subitem_description": "The Fajans method described in the Japanese Pharmacopoeia has been improved for clear coloration at the end point of argentimetry. The pK_a value of fluorescein as an indicator in this method was spectroscopically found to be 6.67. In this method, the end point is difficult to discern owing to suppression of the acid dissociation of the indicator in titrated solution. The sensitivity and accuracy of coloration at the end point were evaluated in these methods using various buffer solutions to find means to enhance the accuracy of the Fajans method, the results indicating that the argentimetry in carbonate buffer solutions is most suitable for discernment of the equivalent point. The desired improvement has been achieved by adding sodium hydrogen carbonate at initial concentration of 0.01 mol/L. The experimental results in this method agreed well with those by the Mohr method in sensitivity of coloration and the equivalent point.", "subitem_description_type": "Other"}]}, "item_1_source_id_13": {"attribute_name": "雑誌書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00053514", "subitem_source_identifier_type": "NCID"}]}, "item_1_text_10": {"attribute_name": "著者所属(英)", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "/////Laboratory of Pharmaceutical Analytical Chemistry, Gifu Pharmaceutical University"}]}, "item_1_text_9": {"attribute_name": "著者所属(日)", "attribute_value_mlt": [{"subitem_text_value": "/////岐阜薬科大学"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "1998-06-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KJ00000073615.pdf", "filesize": [{"value": "454.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 454000.0, "url": {"url": "https://gifu-pu.repo.nii.ac.jp/record/11237/files/KJ00000073615.pdf"}, "version_id": "b1619e42-51c0-4971-a042-97f7c2f40ada"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "\u003c一般論文\u003e日本薬局方収載Fajans法の改良", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "\u003c一般論文\u003e日本薬局方収載Fajans法の改良"}, {"subitem_title": "\u003cRegular Article\u003eImprovement of the Fajans Method Described in the Japanese Pharmacopoeia", "subitem_title_language": "en"}]}, "item_type_id": "1", "owner": "5", "path": ["194"], "permalink_uri": "https://gifu-pu.repo.nii.ac.jp/records/11237", "pubdate": {"attribute_name": "公開日", "attribute_value": "1998-06-30"}, "publish_date": "1998-06-30", "publish_status": "0", "recid": "11237", "relation": {}, "relation_version_is_last": true, "title": ["\u003c一般論文\u003e日本薬局方収載Fajans法の改良"], "weko_shared_id": 5}