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<総説>メソポーラスシリカを活用する有機合成反応の開発に関する研究
https://gifu-pu.repo.nii.ac.jp/records/12739
https://gifu-pu.repo.nii.ac.jp/records/1273921a32bfe-df8f-4e55-bdf5-87655e60fe20
名前 / ファイル | ライセンス | アクション |
---|---|---|
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Item type | 紀要論文(ELS) / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2003-06-30 | |||||
タイトル | ||||||
タイトル | <総説>メソポーラスシリカを活用する有機合成反応の開発に関する研究 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | <Review>Synthetic Organic Chemistry with Mesoporous Silica | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | メソポーラスシリカ | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Ti-HMS | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | MCM-41 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | FSM-16 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 脱保護 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 加速効果 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 酸化的光脱炭酸反応 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 光酸化反応 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | 酸化開裂反応 | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | mesoporous silica | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | HMS | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Ti-HMS | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | MCM-41 | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | FSM-16 | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | deprotection | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | acceleratory effect | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | photodecarboxylation | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | photooxidation | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | oxidative cleavage | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ページ属性 | ||||||
内容記述タイプ | Other | |||||
内容記述 | P(論文) | |||||
論文名よみ | ||||||
その他のタイトル | 〓 | |||||
著者名(日) |
児玉, 朋寛
× 児玉, 朋寛× 伊藤, 彰近× 正木, 幸雄 |
|||||
著者名よみ |
コダマ, トモヒロ
× コダマ, トモヒロ× イトウ, アキチカ× マサキ, ユキオ |
|||||
著者名(英) |
KODAMA, Tomohiro
× KODAMA, Tomohiro× ITOH, Akichika× MASAKI, Yukio |
|||||
著者所属(日) | ||||||
値 | 岐阜薬科大学合成薬品製造学教室/岐阜薬科大学合成薬品製造学教室/岐阜薬科大学合成薬品製造学教室 | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University/Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University/Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University | |||||
抄録(日) | ||||||
内容記述タイプ | Other | |||||
内容記述 | 代表的なメソポーラスシリカとして知られるTi-HMS, MCM-41そしてFSM-16を有機合成反応における反応促進剤として活用することを試みた。ルイス酸サイトを有するTi-HMSが接触還元条件下,選択的に水酸基の脱ベンジル化反応を加速することを見出した。 MCM-41が水酸基の保護基として知られるt-butyldimethylsilyl (TBS)基存在下,triethylsilyl (TES)基を選択的に脱保護できることを見出した。 FSM-16がα-ハイドロキシカルボン酸の酸化的光脱炭酸反応やアリールメチルハライドやアリールメチルアルコールの光酸化反応,スチレン類の酸化開裂反応等幾つかの光反応を促進することを見出した。 | |||||
抄録(英) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Ti-HMS, MCM-41 and FSM-16 which are typical hexagonal mesoporous silica, were investigated for use as a promoter for organic synthesis. Ti-HMS, which possesses Lewis acid sites, was found to accelerate deprotection of the benzyl group, which is a typical protecting group of the hydroxyl group, selectively under hydrogenolytic conditions. MCM-41 proved to deprotect the triethylsilyl (TES) group, which is a typical protecting group of hydroxyl group, selectively and easily in the presence of t-butyldimethylsilyl (TBS) group. FSM-16 was found to accelerate several photo-reactions such as oxidative photodecarboxylation of α-hydroxy carboxylic acid, oxidation of arylmethylhalides and arylmethylalcohols, and oxidative cleavage of styrenes. | |||||
雑誌書誌ID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00053514 | |||||
書誌情報 |
岐阜藥科大學紀要 en : The annual proceedings of Gifu College of Pharmacy 巻 52, p. 1-10, 発行日 2003-06-30 |