{"_buckets": {"deposit": "69d34cd4-7519-449e-ad09-61c85fb3a1e2"}, "_deposit": {"created_by": 5, "id": "12739", "owners": [5], "pid": {"revision_id": 0, "type": "depid", "value": "12739"}, "status": "published"}, "_oai": {"id": "oai:gifu-pu.repo.nii.ac.jp:00012739", "sets": ["199"]}, "author_link": ["17734", "13220", "17980", "13219", "17733", "8841", "17798", "17735", "17984"], "item_1_alternative_title_5": {"attribute_name": "論文名よみ", "attribute_value_mlt": [{"subitem_alternative_title": "〓"}]}, "item_1_biblio_info_14": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2003-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "10", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "52", "bibliographic_titles": [{"bibliographic_title": "岐阜藥科大學紀要"}, {"bibliographic_title": "The annual proceedings of Gifu College of Pharmacy", "bibliographic_titleLang": "en"}]}]}, "item_1_creator_6": {"attribute_name": "著者名(日)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "児玉, 朋寛"}], "nameIdentifiers": [{"nameIdentifier": "17733", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "伊藤, 彰近"}], "nameIdentifiers": [{"nameIdentifier": "17798", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "正木, 幸雄"}], "nameIdentifiers": [{"nameIdentifier": "13219", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_7": {"attribute_name": "著者名よみ", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "コダマ, トモヒロ"}], "nameIdentifiers": [{"nameIdentifier": "17734", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "イトウ, アキチカ"}], "nameIdentifiers": [{"nameIdentifier": "17980", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "マサキ, ユキオ"}], "nameIdentifiers": [{"nameIdentifier": "13220", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_creator_8": {"attribute_name": "著者名(英)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "KODAMA, Tomohiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "17735", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ITOH, Akichika", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "17984", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "MASAKI, Yukio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "8841", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_description_1": {"attribute_name": "ページ属性", "attribute_value_mlt": [{"subitem_description": "P(論文)", "subitem_description_type": "Other"}]}, "item_1_description_11": {"attribute_name": "抄録(日)", "attribute_value_mlt": [{"subitem_description": "代表的なメソポーラスシリカとして知られるTi-HMS, MCM-41そしてFSM-16を有機合成反応における反応促進剤として活用することを試みた。ルイス酸サイトを有するTi-HMSが接触還元条件下,選択的に水酸基の脱ベンジル化反応を加速することを見出した。 MCM-41が水酸基の保護基として知られるt-butyldimethylsilyl (TBS)基存在下,triethylsilyl (TES)基を選択的に脱保護できることを見出した。 FSM-16がα-ハイドロキシカルボン酸の酸化的光脱炭酸反応やアリールメチルハライドやアリールメチルアルコールの光酸化反応,スチレン類の酸化開裂反応等幾つかの光反応を促進することを見出した。", "subitem_description_type": "Other"}]}, "item_1_description_12": {"attribute_name": "抄録(英)", "attribute_value_mlt": [{"subitem_description": "Ti-HMS, MCM-41 and FSM-16 which are typical hexagonal mesoporous silica, were investigated for use as a promoter for organic synthesis. Ti-HMS, which possesses Lewis acid sites, was found to accelerate deprotection of the benzyl group, which is a typical protecting group of the hydroxyl group, selectively under hydrogenolytic conditions. MCM-41 proved to deprotect the triethylsilyl (TES) group, which is a typical protecting group of hydroxyl group, selectively and easily in the presence of t-butyldimethylsilyl (TBS) group. FSM-16 was found to accelerate several photo-reactions such as oxidative photodecarboxylation of α-hydroxy carboxylic acid, oxidation of arylmethylhalides and arylmethylalcohols, and oxidative cleavage of styrenes.", "subitem_description_type": "Other"}]}, "item_1_source_id_13": {"attribute_name": "雑誌書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00053514", "subitem_source_identifier_type": "NCID"}]}, "item_1_text_10": {"attribute_name": "著者所属(英)", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University/Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University/Laboratory of Synthetic Organic Chemistry, Gifu Pharmaceutical University"}]}, "item_1_text_9": {"attribute_name": "著者所属(日)", "attribute_value_mlt": [{"subitem_text_value": "岐阜薬科大学合成薬品製造学教室/岐阜薬科大学合成薬品製造学教室/岐阜薬科大学合成薬品製造学教室"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2003-06-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KJ00000074420.pdf", "filesize": [{"value": "932.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 932200.0, "url": {"label": "KJ00000074420", "url": "https://gifu-pu.repo.nii.ac.jp/record/12739/files/KJ00000074420.pdf"}, "version_id": "ea842215-0984-43bd-8e4f-d1900e156ed7"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "メソポーラスシリカ", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Ti-HMS", "subitem_subject_scheme": "Other"}, {"subitem_subject": "MCM-41", "subitem_subject_scheme": "Other"}, {"subitem_subject": "FSM-16", "subitem_subject_scheme": "Other"}, {"subitem_subject": "脱保護", "subitem_subject_scheme": "Other"}, {"subitem_subject": "加速効果", "subitem_subject_scheme": "Other"}, {"subitem_subject": "酸化的光脱炭酸反応", "subitem_subject_scheme": "Other"}, {"subitem_subject": "光酸化反応", "subitem_subject_scheme": "Other"}, {"subitem_subject": "酸化開裂反応", "subitem_subject_scheme": "Other"}, {"subitem_subject": "mesoporous silica", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "HMS", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Ti-HMS", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "MCM-41", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "FSM-16", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "deprotection", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "acceleratory effect", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photodecarboxylation", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photooxidation", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "oxidative cleavage", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "\u003c総説\u003eメソポーラスシリカを活用する有機合成反応の開発に関する研究", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "\u003c総説\u003eメソポーラスシリカを活用する有機合成反応の開発に関する研究"}, {"subitem_title": "\u003cReview\u003eSynthetic Organic Chemistry with Mesoporous Silica", "subitem_title_language": "en"}]}, "item_type_id": "1", "owner": "5", "path": ["199"], "permalink_uri": "https://gifu-pu.repo.nii.ac.jp/records/12739", "pubdate": {"attribute_name": "公開日", "attribute_value": "2003-06-30"}, "publish_date": "2003-06-30", "publish_status": "0", "recid": "12739", "relation": {}, "relation_version_is_last": true, "title": ["\u003c総説\u003eメソポーラスシリカを活用する有機合成反応の開発に関する研究"], "weko_shared_id": 5}