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Highly Selective Synthesis of cis‐2,2,4,4‐Tetramethylcyclobutane‐1,3‐diol via Solvent‐Free Hydrogenation and Isomerization
https://gifu-pu.repo.nii.ac.jp/records/14708
https://gifu-pu.repo.nii.ac.jp/records/14708dff64e6e-e08e-46a7-8fb1-e5f926cf7641
| Item type | 研究室原著論文(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2023-03-08 | |||||
| タイトル | ||||||
| タイトル | Highly Selective Synthesis of cis‐2,2,4,4‐Tetramethylcyclobutane‐1,3‐diol via Solvent‐Free Hydrogenation and Isomerization | |||||
| タイトル | ||||||
| タイトル | Highly Selective Synthesis of cis‐2,2,4,4‐Tetramethylcyclobutane‐1,3‐diol via Solvent‐Free Hydrogenation and Isomerization | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 抄録 | ||||||
| 値 | In this study, ruthenium-on-carbon-catalyzed hydrogenation of CBDK was developed for the production of cis-CBDO under solvent-free conditions. Isomerization using a ruthenium catalyst and hydrogen gas may improve the selective formation of cis-CBDO. Moreover, the reaction mechanisms for cis-selectivity was proposed based on density functional theory (DFT) calculations. | |||||
| 書誌情報 |
en : Asian Journal of Organic Chemistry 巻 11, 号 9, 発行日 2022 |
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| DOI | ||||||
| 値 | 10.1002/ajoc.202200263 | |||||
