{"_buckets": {"deposit": "4e63629e-5ba0-4a62-84e0-dafa8ca1c112"}, "_deposit": {"created_by": 5, "id": "10131", "owners": [5], "pid": {"revision_id": 0, "type": "depid", "value": "10131"}, "status": "published"}, "_oai": {"id": "oai:gifu-pu.repo.nii.ac.jp:00010131", "sets": ["191"]}, "author_link": ["15118"], "item_1_biblio_info_14": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1995-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "17", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "44", "bibliographic_titles": [{"bibliographic_title": "岐阜藥科大學紀要"}, {"bibliographic_title": "The annual proceedings of Gifu College of Pharmacy", "bibliographic_titleLang": "en"}]}]}, "item_1_creator_8": {"attribute_name": "著者名(英)", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "ARAI, YOSHITSUGU", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "15118", "nameIdentifierScheme": "WEKO"}]}]}, "item_1_description_1": {"attribute_name": "ページ属性", "attribute_value_mlt": [{"subitem_description": "P(論文)", "subitem_description_type": "Other"}]}, "item_1_description_12": {"attribute_name": "抄録(英)", "attribute_value_mlt": [{"subitem_description": "This review reports on our recent studies on asymmetric Diels-Alder reactions of chiral α, β-unsaturated sulfoxides. For the preparation of these sulfoxides as Diels-Alder dienophiles, the Andersen method as well as a novel route by diastereoselective oxidation of 2-exo-hydroxy-10-bornyl vinyl sulfides with 3-chloroperoxybenzoic acid is presented. The latter methodology has been successfully applied to synthesis of two types of novel sulfoxides bearing labile fuctionality, I.e., α-sulfinylmaleate and α -sulfinylmaleimide derivatives. These sulfinyl dienophiles effect Diels-Alder reactions with a high degree of diastereoselectivity. Especially, the chiral α-sulfinylmaleimides readily react with Diels-Alder dienes of rather low reactivity, to give the corresponding cycloadducts under conventional conditions. Also described are applications of these asymmetric Diels-Alder reactions to natural product synthesis.", "subitem_description_type": "Other"}]}, "item_1_source_id_13": {"attribute_name": "雑誌書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00053514", "subitem_source_identifier_type": "NCID"}]}, "item_1_text_10": {"attribute_name": "著者所属(英)", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "Laboratory of Pharmaceutical Synthetic Chemistry, Gifu Pharmaceutical University"}]}, "item_1_text_9": {"attribute_name": "著者所属(日)", "attribute_value_mlt": [{"subitem_text_value": "岐阜薬科大学"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "1995-06-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KJ00000073153.pdf", "filesize": [{"value": "776.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 776100.0, "url": {"url": "https://gifu-pu.repo.nii.ac.jp/record/10131/files/KJ00000073153.pdf"}, "version_id": "133f3767-9af7-46f0-a48c-c725479aee5d"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "\u003cReview\u003eAsymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "\u003cReview\u003eAsymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles", "subitem_title_language": "en"}]}, "item_type_id": "1", "owner": "5", "path": ["191"], "permalink_uri": "https://gifu-pu.repo.nii.ac.jp/records/10131", "pubdate": {"attribute_name": "公開日", "attribute_value": "1995-06-30"}, "publish_date": "1995-06-30", "publish_status": "0", "recid": "10131", "relation": {}, "relation_version_is_last": true, "title": ["\u003cReview\u003eAsymmetric Diels-Alder Reactions Using Chiral α, β-Unsaturated Sulfoxides as Efficient Dienophiles"], "weko_shared_id": -1}