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<総説>電子求引基で安定化されたセレナベンゼンの合成に関する研究
https://gifu-pu.repo.nii.ac.jp/records/12604
https://gifu-pu.repo.nii.ac.jp/records/1260431823f7b-fd81-4ace-b9d4-df0ad0f280f6
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文(ELS) / Departmental Bulletin Paper(1) | |||||
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公開日 | 2002-06-30 | |||||
タイトル | ||||||
タイトル | <総説>電子求引基で安定化されたセレナベンゼンの合成に関する研究 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | <Review>Synthesis of Selenabenzenes Stabilized by Electron-withdrawing Groups | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ページ属性 | ||||||
内容記述タイプ | Other | |||||
内容記述 | P(論文) | |||||
論文名よみ | ||||||
その他のタイトル | 〓 | |||||
著者名(日) |
本多, 栄治
× 本多, 栄治× 片岡, 貞 |
|||||
著者名よみ |
ホンダ, エイジ
× ホンダ, エイジ× カタオカ, タダシ |
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著者名(英) |
HONDA, Eiji
× HONDA, Eiji× KATAOKA, Tadashi |
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著者所属(日) | ||||||
値 | 岐阜薬科大学/岐阜薬科大学 | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Laboratory of Analytical Pharmaceutical Chemistry, Gifu Pharmaceutical University/Laboratory of Analytical Pharmaceutical Chemistry, Gifu Pharmaceutical University | |||||
抄録(日) | ||||||
内容記述タイプ | Other | |||||
内容記述 | 活発な研究が行われているヘテロベンゼンのなかで,セレナベンゼンは未だ安定に単離されていなかったが,電子求引基によって安定化されたセレナベンゼンが,本研究で初めて空気中室温で安定に単離された。セレナベンゼンの反応を行い,化学的性質を解明するとともに,各種機器スペクトルデータ,X線結晶構造解析によりその構造を明らかにした。 | |||||
抄録(英) | ||||||
内容記述タイプ | Other | |||||
内容記述 | The chemistry of heterobenzenes is one of the interesting research fields in heterocyclic chemistry and recently attention has been focused on them. Selenabenzenes with two electron-withdrawing groups (EWGs) at 2- and 6-positions 44a-c were synthesized from dihalides 25a, 25b and 25c' via 7 steps and isolated as stable compounds at room temperatwe. According to X-ray structual analysis of a benzoyl derivative 44c, the six membered ring containing a selenium atom was almost planar and the structure of the selenium atom was tetrahedral with four sp^3 hybridized orbitals. | |||||
雑誌書誌ID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00053514 | |||||
書誌情報 |
岐阜藥科大學紀要 en : The annual proceedings of Gifu College of Pharmacy 巻 51, p. 1-12, 発行日 2002-06-30 |